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Hydrogen

Question
CBSEENCH11006909

Saline hydrides are known to react with water violently producing fire. Can CO2, a well-known fire extinguisher, be used in this case? Explain.

Solution
CO2 can not be used as a fire extinguisher. This is because saline hydrides (such as NaH, CaHetc.) react with water violently producing corresponding metal hydrides and dihydrogen.
NaH left parenthesis straight s right parenthesis space plus space straight H subscript 2 straight O left parenthesis l right parenthesis space space rightwards arrow space space space NaOH left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis
CaH subscript 2 left parenthesis straight s right parenthesis space plus space 2 straight H subscript 2 straight O left parenthesis straight l right parenthesis space rightwards arrow space space space Ca left parenthesis OH right parenthesis subscript 2 left parenthesis aq right parenthesis space plus space 2 straight H subscript 2 left parenthesis straight g right parenthesis
The above reactions are highly exothermic that evolved H2 immediately catches fire. This fire can not be extinguished by CO2 because it gets reduced by the hot metal hydride.
NaH space plus space CO subscript 2 space space rightwards arrow space HCOONa
On the other hand sand (being a stable solid) can be used for extinguishing fire.