-->

Hydrogen

Question
CBSEENCH11006880

How would you prepare dihydrogen from a substance other than water?

Solution
1. From acids. Active metals such as Zn, Fe, Mg etc. react with dilute mineral acids (HCl, H2SOetc.) to produce dihydrogen gas.
Zn left parenthesis straight s right parenthesis space plus straight H subscript 2 SO subscript 4 left parenthesis aq right parenthesis space space rightwards arrow space space space ZnSO subscript 4 left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis
Mg left parenthesis straight s right parenthesis space plus space 2 HCl left parenthesis aq right parenthesis space space space rightwards arrow space space MgCl subscript 2 left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis
Fe left parenthesis straight s right parenthesis space plus space 2 HCl left parenthesis aq right parenthesis space space rightwards arrow space space FeCl subscript 2 left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis
Since metals have displaced hydrogen from the acids, hence their reactions are called displacement reactions.
2. From alkalies: Metals like Zn, Al, Sn, Pb, Sb etc. react with boiling sodium hydroxide solution to liberate hydrogen gas.
Zn left parenthesis straight s right parenthesis space plus space 2 NaOH left parenthesis aq right parenthesis space space rightwards arrow space space space stack Na subscript 2 ZnO subscript 2 left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis with Sodium space zincate below
2 Al left parenthesis straight s right parenthesis plus 2 NaOH left parenthesis aq right parenthesis plus 2 straight H subscript 2 straight O left parenthesis straight l right parenthesis space space rightwards arrow space space stack 2 NaAlO subscript 2 left parenthesis aq right parenthesis with Sodium space meta space aluminate below plus 3 straight H subscript 2 left parenthesis straight g right parenthesis
Sn left parenthesis straight s right parenthesis space plus space 2 NaOH left parenthesis aq right parenthesis space space rightwards arrow space space space stack Na subscript 2 SnO subscript 2 left parenthesis aq right parenthesis with Sodium space stannite below space plus space straight H subscript 2 left parenthesis straight g right parenthesis