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Redox Reactions

Question
CBSEENCH11006798

What is electrode potential? Name the factors on which it depends.

Solution
The tendency of an electrode to lose or gain electrons when in contact with the solution of its own ions is known as electrode potential. The tendency of an electrode to lose electrons is a direct measure of its tendency to get oxidised. This tendency is known as oxidation potential.
straight M left parenthesis straight s right parenthesis space space space rightwards harpoon over leftwards harpoon space space space straight M to the power of straight n plus end exponent space left parenthesis aq right parenthesis space plus space ne to the power of minus
Zn left parenthesis straight s right parenthesis space space rightwards harpoon over leftwards harpoon space space Zn to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus space 2 straight e to the power of minus
straight H subscript 2 space space space space space space rightwards harpoon over leftwards harpoon space 2 straight H to the power of plus left parenthesis aq right parenthesis space plus space 2 straight e to the power of minus
The tendency of an electrode to gain electron is a direct measure of its tendency to get reduced. This tendency is known as reduction potential.
straight M to the power of straight n plus end exponent left parenthesis aq right parenthesis space plus space ne to the power of minus space space space space rightwards harpoon over leftwards harpoon space space space space straight M left parenthesis straight s right parenthesis
Cu to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus space 2 straight e to the power of minus space space rightwards harpoon over leftwards harpoon space space Cu left parenthesis straight s right parenthesis
2 straight H to the power of plus left parenthesis aq right parenthesis space plus space 2 straight e to the power of minus space space rightwards harpoon over leftwards harpoon space space space straight H subscript 2 left parenthesis straight g right parenthesis
It is clear that the oxidation potential is the reverse of reduction potential. For example, if reduction potential of zinc is –0.76V, its oxidation potential is +0.76V.
In general, for an electrode,
Oxidation potential =–Reduction potential
The magnitude of electrode potential depends on upon three factors:
(i) Nature of electrode
(ii) Concentration of the metal ion
(iii) Temperature.
Since the electrode potentials depend on upon the concentration of the metal ions in solution and temperature, therefore electrode potential are generally measured under standard conditions i.e. 1 molar concentration of metal ions (1 mol L-1) and a temperature of 298K and are called standard electrode potentials and denoted by E°.