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Redox Reactions

Question
CBSEENCH11006797

Split the following redox reactions in oxidation and reduction half reactions:
left parenthesis straight a right parenthesis space 2 straight K left parenthesis straight s right parenthesis space plus space Cl subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space space 2 KCl left parenthesis straight s right parenthesis
left parenthesis straight b right parenthesis space 2 Al left parenthesis straight s right parenthesis space plus space 3 Cu to the power of 2 plus end exponent left parenthesis aq right parenthesis space space rightwards arrow space space space 2 Al to the power of 3 plus end exponent left parenthesis aq right parenthesis space plus space 3 Cu left parenthesis straight s right parenthesis

Solution

(a) The given reaction
             2 straight K left parenthesis straight s right parenthesis space plus space Cl subscript 2 left parenthesis straight g right parenthesis space space space rightwards arrow space space space 2 KCl left parenthesis straight s right parenthesis
can space be space split space into space two space half space reaction space as colon
(i) Oxidation half-reaction.
                               2 straight K space rightwards arrow space space 2 straight K to the power of plus space plus space 2 straight e to the power of minus
(ii) Reduction half reaction:
                              Cl subscript 2 space plus space 2 straight e to the power of minus space space rightwards arrow space space space 2 Cl to the power of minus
(b) The given reaction
          2 Al left parenthesis straight s right parenthesis space plus space 3 Cu to the power of 2 plus end exponent left parenthesis aq right parenthesis space space space rightwards arrow space space space 2 Al to the power of 3 plus end exponent left parenthesis aq right parenthesis space plus space 3 Cu left parenthesis straight s right parenthesis
can space be space split space into space two space half space reaction colon
(i) Oxidation half reaction:
                    2 Al left parenthesis straight s right parenthesis space space rightwards arrow space space space 2 Al to the power of 3 plus end exponent left parenthesis aq right parenthesis space plus 6 straight e to the power of minus
(ii) Reduction half reaction:
               3 Cu to the power of 2 plus end exponent space plus space 6 straight e to the power of minus space space space rightwards arrow space space space 3 Cu left parenthesis straight s right parenthesis