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Redox Reactions

Question
CBSEENCH11006789

Explain the function of salt bridge in an electrochemical cell.

Solution

The safe bridge is an inverted U-shaped glass tube filled with strong electrolytes (NH4NO3, KCl, KNO3 etc.) dissolved in a gelatinous substance. The functions of the salt bridge are:
(i) To complete the circuit.
(ii) To maintain electrical neutrality of the two half-cell solutions and ensure a continuous production of electric current in a galvanic cell.
Let us consider Daniell cell,
Zn left parenthesis straight s right parenthesis space plus space Cu to the power of 2 plus end exponent left parenthesis aq right parenthesis space space rightwards arrow space space space Zn to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus space Cu left parenthesis straight s right parenthesis
In the oxidation half-cell, Zn will lose electrons and would change to Zn2+ ions. So positive charge may accumulate in this half cell due to an excess of Zn2+ ions. This prevents the release of electrons from zinc plate and flow of electricity stops. Similarly, the cathodic half cell, Cu2+ ions would gain electrons and deposited as Cu on the cathode. So the negative charge would accumulate due to an excess of SO subscript 4 superscript 2 minus end superscript ions in the half cell. This prevents the flow of electrons to the copper plate. This also stops the flow of electric current. The salt bridge then supplies negative ions to the oxidation half-cell in order to neutralise excess of Zn2+ ions. Similarly, it supplies positive ions to the reduction half-cell in order to neutralise the excess of sulphate ions. Thus, salt bridge maintains the electrical neutrality in both the half cells.