Question
Permanganate (VII) ion, in basic solution oxidises iodide ion, I- to produce molecule iodine (I2) and manganese (IV) oxide (MnO2). Write a balanced ionic equation to represent redox reaction.
Solution
The skeleton ionic equation is

1. Write the oxidation and reduction half-reactions by observing the changes in oxidation number and writing these separately.
Oxidation half reaction:
-1 0
I-(aq)
I2(s)
Reduction half reaction:
+7 +4

2. Balance the oxidation half reaction
(i) Balance 1 atoms by multiplying I- by 2
-1 0

(ii) Add 2 electrons towards R.H.S. to balance the charges on iodine atoms

3. Balancing the reduction half reaction
(i) Add 3 electrons towards L.H.S. to balance the charge on Mn

(ii) Balance O atoms by adding two H2O molecules towards R.H.S.

(iii) Balance H atoms by adding four H+ towardS
L.H.S.

Since the reaction takes place in a basic solution, therefore for four H+ ions, we add four OH- ions to both sides of the equation.

[Balanced reduction half reaction]
4. Multiply balanced oxidation half-reaction by 3 and balanced reduction half-reaction by 2 and add both the half reactions.

This is a balanced equation.

1. Write the oxidation and reduction half-reactions by observing the changes in oxidation number and writing these separately.
Oxidation half reaction:
-1 0
I-(aq)

Reduction half reaction:
+7 +4

2. Balance the oxidation half reaction
(i) Balance 1 atoms by multiplying I- by 2
-1 0

(ii) Add 2 electrons towards R.H.S. to balance the charges on iodine atoms

3. Balancing the reduction half reaction
(i) Add 3 electrons towards L.H.S. to balance the charge on Mn

(ii) Balance O atoms by adding two H2O molecules towards R.H.S.

(iii) Balance H atoms by adding four H+ towardS
L.H.S.

Since the reaction takes place in a basic solution, therefore for four H+ ions, we add four OH- ions to both sides of the equation.

[Balanced reduction half reaction]
4. Multiply balanced oxidation half-reaction by 3 and balanced reduction half-reaction by 2 and add both the half reactions.

This is a balanced equation.