Question
Balance the following equation by half reaction method:

Solution
(1) Write the oxidation and reduction half-reactions by observing the changes in oxidation numbers and write these separately.
-2 0
Oxidation half-reaction: H2S
S
+5 +2
Reduction half-reaction: HNO3
NO
(2) To balance the oxidation half reaction. (i) Balancing of S is not required as the number of each S is one on both the sides.
2- 0
H2S
S
(ii) Add two electrons towards R.H.S. to balance the charges on sulphur atom.
2- 0

(iii) Balance H atoms by adding two H+ towards
R.H.S.
2- 0
+ 
(Balanced oxidation half reduction)
(3) To balance the reduction half reaction
(i) Balancing of N is not required as the number of each N is one on both the sides.
+ 5 +2
HNO3
NO
(ii) Add 3 electrons towards L.H.S. in order to balance the charges on the nitrogen atom.
+5 +2
HNO3 + 3e-
NO
(iii) Balance the O atoms by adding two H2O molecules on R.H.S.
+2
HNO3 + 3e-
NO + 2H2O
(iv) Balancing H atoms by adding 3H+ on L.H.S.
(Balancing reduction half reaction)
4. Multiplying oxidation half-reaction by 3 and reductive half-reaction by 2 to equate the electrons and adding both the half reactions.

This is a balanced redox reaction.
-2 0
Oxidation half-reaction: H2S

+5 +2
Reduction half-reaction: HNO3

(2) To balance the oxidation half reaction. (i) Balancing of S is not required as the number of each S is one on both the sides.
2- 0
H2S

(ii) Add two electrons towards R.H.S. to balance the charges on sulphur atom.
2- 0

(iii) Balance H atoms by adding two H+ towards
R.H.S.
2- 0


(Balanced oxidation half reduction)
(3) To balance the reduction half reaction
(i) Balancing of N is not required as the number of each N is one on both the sides.
+ 5 +2
HNO3

(ii) Add 3 electrons towards L.H.S. in order to balance the charges on the nitrogen atom.
+5 +2
HNO3 + 3e-

(iii) Balance the O atoms by adding two H2O molecules on R.H.S.
+2
HNO3 + 3e-

(iv) Balancing H atoms by adding 3H+ on L.H.S.
(Balancing reduction half reaction)
4. Multiplying oxidation half-reaction by 3 and reductive half-reaction by 2 to equate the electrons and adding both the half reactions.

This is a balanced redox reaction.