-->

Redox Reactions

Question
CBSEENCH11006775

Balance the following equation by half reaction method:
straight H subscript 2 straight S space plus space HNO subscript 3 space space rightwards arrow space space space NO space plus space straight S space plus space straight H subscript 2 straight O
 

Solution
(1) Write the oxidation and reduction half-reactions by observing the changes in oxidation numbers and write these separately.
                                      -2             0
Oxidation half-reaction:   H2S    rightwards arrow   S
                                     
                                      +5           +2
Reduction half-reaction:     HNO3  rightwards arrow  NO
(2) To balance the oxidation half reaction. (i) Balancing of S is not required as the number of each S is one on both the sides.
               2-             0
           H2S    rightwards arrow     S
(ii) Add two electrons towards R.H.S. to balance the charges on sulphur atom.
                     2-           0
                    straight H subscript 2 straight S space space rightwards arrow space space space space straight S space plus space 2 straight e to the power of minus
(iii) Balance H atoms by adding two H+ towards 
R.H.S.
           2-        0
          straight H subscript 2 straight S space rightwards arrow space space straight S    + 2 straight e to the power of minus space plus space 2 straight H to the power of plus
   (Balanced oxidation half reduction)
(3) To balance the reduction half reaction
(i) Balancing of N is not required as the number of each N is one on both the sides.
                          + 5           +2
                         HNO3    rightwards arrow  NO
(ii) Add 3 electrons towards L.H.S. in order to balance the charges on the nitrogen atom. 
            +5                  +2
        HNO3   + 3e-   rightwards arrow NO
(iii) Balance the O atoms by adding two H2O molecules on R.H.S.
                                       +2
           HNO3 + 3e-  rightwards arrow     NO + 2H2O
(iv) Balancing H atoms by adding 3H+ on L.H.S.
                             (Balancing reduction half reaction)
4. Multiplying oxidation half-reaction by 3 and reductive half-reaction by 2 to equate the electrons and adding both the half reactions. 
      space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space straight H subscript 2 straight S space rightwards arrow space space space straight S space plus space 2 straight e to the power of minus space plus space 2 straight H to the power of plus right square bracket space cross times space 3
space space space space HNO subscript 3 space plus space 3 straight e to the power of minus space plus space 3 straight H to the power of plus space space space rightwards arrow space space space NO space plus space 2 straight H subscript 2 straight O right square bracket space cross times space 2
___________________________________________________
3 straight H subscript 2 straight S space plus space 2 HNO subscript 3 space space rightwards arrow space space space space 3 straight S space plus space 2 NO space plus space 4 straight H subscript 2 straight O
This is a balanced redox reaction.