Question
Balance the equation by half reaction method:
Solution
1. Write the oxidation and reduction half-reactions by observing the changes in oxidation numbers and write these separately.
0 +5
Oxidation half-reaction:
0
Reduction half-reaction:
2. Balancing the oxidation half reaction.
(i) Balance 1 atoms by multiplying
by 2.
0 +5

(ii) Add 10 electrons towards R.H.S. to balance the charges on iodine atoms,
0 +5

(iii) Since the medium is alkaline, 6H2O molecules are added towards R.H.S. and 12 OH-ions towards L.H.S. in order to balance oxygen and hydrogen atoms.

3. Balancing the reduction half reaction.
(i) Balancing 1 atoms by multiplying I- by
2. 0 +5

(ii) Add two electrons towards L.H.S. in order to balance the charges on iodine atoms

4. Multiplying reduction half-reaction by 5 to equate the electrons and add both the half reactions.

This is a balanced redox reaction.
0 +5
Oxidation half-reaction:

0
Reduction half-reaction:

2. Balancing the oxidation half reaction.
(i) Balance 1 atoms by multiplying

0 +5

(ii) Add 10 electrons towards R.H.S. to balance the charges on iodine atoms,
0 +5

(iii) Since the medium is alkaline, 6H2O molecules are added towards R.H.S. and 12 OH-ions towards L.H.S. in order to balance oxygen and hydrogen atoms.

3. Balancing the reduction half reaction.
(i) Balancing 1 atoms by multiplying I- by
2. 0 +5

(ii) Add two electrons towards L.H.S. in order to balance the charges on iodine atoms

4. Multiplying reduction half-reaction by 5 to equate the electrons and add both the half reactions.

This is a balanced redox reaction.