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Redox Reactions

Question
CBSEENCH11006754

Compute the oxidation number of:
(i) Ni in |Ni(Fe(C2O4)3|
(ii) Fe in K3|Fe(C2O4)3|

Solution

(i) Let the oxidation number of Ni = x
Writing the oxidation number of each atom at the top of its symbol. 
                          x       0
                         [Ni  (CO)4]
The algebraic sum of the oxidation number of various atoms = 0
                  x + 4(0) = 0
                          x = 0
(ii) Let the oxidation number of Fe = x
Writing the oxidation number of each atom at the top of its symbol,
                        +1                  x - 2
                         K3               [Fe(C2O4)3]
The algebraic sum of the oxidation number of various atoms = 0
          3(+1) + x + 3(-2) = 0
                  3 + x - 6 = 0
therefore space space space space space space space straight x space equals space plus 3