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Redox Reactions

Question
CBSEENCH11006734

What is the oxidation number of sulphur in:
(i)H2SO4            (ii)        Na2S2O3?

Solution

(i) H2SO4:
Let the oxidation number of S = x
Writing the oxidation number of each atom at the top of its symbol
+1             x             -2
H2             S              O4
The algebraic sum of the oxidation number of various atoms = 0
2(+1) + x + 4(-2) = 0
              x - 6  = 0
                   x = +6
(ii) Na2S2O2:
Let the oxidation number of S = x
Writing the oxidation number of each atom at the top of its symbol.
               +1             x            -2
              Na2            S2            O3
The algebraic sum of the oxidation number of various atoms  = 0
                       2(+1) + 2(x) + 3(-2) = 0
or                           2 + 2x - 6 = 0
space space therefore                                 x = +2