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Redox Reactions

Question
CBSEENCH11006697

In the following reactions:
space space left parenthesis straight i right parenthesis space straight H subscript 2 straight O space plus space 2 FeCl subscript 3 space space space space space rightwards arrow space space space space 2 FeCl subscript 2 space plus space 2 HCl space plus space straight S
space space left parenthesis ii right parenthesis space 2 Al space plus space Fe subscript 2 straight O subscript 3 space space rightwards arrow space space space Al subscript 2 straight O subscript 3 space plus space 2 Fe

which is oxidised to what and which is reduced to what? Also, mention the oxidising and reducing agent.

Solution

Here, H2S reduces FeCl3 to FeCl2 while itself gets oxidised to S. Conversely, FeCl3oxidises H2S to S while itself gets reduced to FeCl2. Therefore H2S acts as a reducing agent while FeCl3 acts as an oxidising agent.

Here, Al reduces Fe2O3 to Fe while itself gets oxidised to Al2O3. Conversely, Fe2Ooxidises Al to Al2O3 while itself gets reduced to Fe. Therefore Al acts as a reducing agent while Fe2O3 acts as an oxidising agent.