Question
What do you understand by ionic product of water?
Solution
Water is a weak electrolyte. It dissociates to small extent to give H3O+ (aq) and OH– (aq) ions as represented below:
![<pre>uncaught exception: <b>Http Error #404</b><br /><br />in file: /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/com/wiris/plugin/impl/HttpImpl.class.php line 61<br />#0 [internal function]: com_wiris_plugin_impl_HttpImpl_0(Object(com_wiris_plugin_impl_HttpImpl), NULL, 'http://www.wiri...', 'Http Error #404')
#1 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/php/Boot.class.php(769): call_user_func_array('com_wiris_plugi...', Array)
#2 [internal function]: _hx_lambda->execute('Http Error #404')
#3 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/haxe/Http.class.php(532): call_user_func_array(Array, Array)
#4 [internal function]: haxe_Http_5(true, Object(com_wiris_plugin_impl_HttpImpl), Object(com_wiris_plugin_impl_HttpImpl), Array, Object(haxe_io_BytesOutput), true, 'Http Error #404')
#5 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/php/Boot.class.php(769): call_user_func_array('haxe_Http_5', Array)
#6 [internal function]: _hx_lambda->execute('Http Error #404')
#7 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/com/wiris/plugin/impl/HttpImpl.class.php(27): call_user_func_array(Array, Array)
#8 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/haxe/Http.class.php(444): com_wiris_plugin_impl_HttpImpl->onError('Http Error #404')
#9 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/haxe/Http.class.php(458): haxe_Http->customRequest(true, Object(haxe_io_BytesOutput), NULL, NULL)
#10 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/com/wiris/plugin/impl/HttpImpl.class.php(40): haxe_Http->request(true)
#11 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/lib/com/wiris/plugin/impl/TextServiceImpl.class.php(80): com_wiris_plugin_impl_HttpImpl->request(true)
#12 /home/config_admin/public/felixventures.in/public/application/css/plugins/tiny_mce_wiris/integration/service.php(19): com_wiris_plugin_impl_TextServiceImpl->service('mathml2accessib...', Array)
#13 {main}</pre>](/application/zrc/images/qvar/CHEN11090154.png)
Applying the law of chemical equilibrium,
Since the degree of dissociation of water is low, so its concentration remains practically unchanged. Thus [H2O] may be taken as constant.
K × [H2O]2 = [H3O+][OH–]
or Kw = [H3O+][OH–]
where KM,is constant and is known as an ionic product of water. It may be defined as the product of the hydronium ion concentration and hydroxyl ion concentration at a given temperature. The value of Kw at 298K is 1·008 × 10–14 mol2 L–2.
Applying the law of chemical equilibrium,
Since the degree of dissociation of water is low, so its concentration remains practically unchanged. Thus [H2O] may be taken as constant.
K × [H2O]2 = [H3O+][OH–]
or Kw = [H3O+][OH–]
where KM,is constant and is known as an ionic product of water. It may be defined as the product of the hydronium ion concentration and hydroxyl ion concentration at a given temperature. The value of Kw at 298K is 1·008 × 10–14 mol2 L–2.
