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Equilibrium

Question
CBSEENCH11006420

The ionisation constant of acetic acid is 1.74 x10-5. calculate the degree of dissociation of acetic acid in its 0.05M solution. calculate the concentration of acetate ion in the solution and its pH.

Solution

Acetic space space acid space being space straight a space weak space acid comma space Ostwald apostrophe straight s space dilution
space law space is space applicable
straight alpha space equals square root of straight K subscript straight alpha over straight c end root space equals square root of fraction numerator 1.74 space straight x 10 to the power of negative 5 end exponent over denominator 0.05 end fraction end root space equals 0.0186

left square bracket Ac to the power of minus right square bracket space equals square root of straight c straight K subscript straight a space equals square root of 0.05 straight x 1.74 straight x 10 to the power of negative 5 end exponent end root
space equals 9.3 space straight x 10 to the power of negative 4 end exponent space straight M equals 0.00093 space straight M
left square bracket straight H to the power of plus right square bracket space equals left square bracket Ac to the power of minus right square bracket space equals 9.3 space straight x 10 to the power of negative 4 end exponent space straight M
pH equals negative log left square bracket straight H to the power of plus right square bracket space equals negative log 9.3 straight x 10 to the power of negative 1 end exponent
equals 3.03