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Equilibrium

Question
CBSEENCH11006492

What is a degree of ionisation ?

Solution
Some substances when dissolved in water form positive and negative ions. The breaking of the substances into ions, when dissolved in a solvent, is called ionisation. The extent to which an electrolyte undergoes ionisation is expressed in terms of degree of ionisation and it may be defined as the fraction of electrolyte which dissociates into ions.
Mathematically,

Degree space of space Ionisation comma
space space left parenthesis straight alpha right parenthesis space equals space fraction numerator Molarity space of space cation space or space anion space over denominator Original space molarity space of space electrolyte end fraction
Clearly, the degree of ionisation is taken per mole of an electrolyte. For example, if 0·5 mole weak acid HA ionises to give 0·02 mole H+ (aq) or 0·02 mole A (aq), the degree of ionisation per mole of the electrolyte.HA would be
HA space stack rightwards harpoon over leftwards harpoon space with Water on top space straight H to the power of plus left parenthesis aq right parenthesis space plus space straight A to the power of minus subscript left parenthesis aq right parenthesis end subscript
straight alpha space equals space fraction numerator 0.02 over denominator 0.5 end fraction space equals space 1 over 25
therefore space space space space Percent space ionisation space equals space 100 over 25 space equals space 4