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Equilibrium

Question
CBSEENCH11006392

The value of Kc for the reaction 3 straight O subscript 2 left parenthesis straight g right parenthesis space space space rightwards harpoon over leftwards harpoon space space space space 2 straight O subscript 3 left parenthesis straight g right parenthesis is 2.0 space cross times space 10 to the power of negative 50 end exponent at 25 degree straight C.  If the equilibrium concentration of straight O subscript 2 in air at 25 degree straight C is 1.6 space cross times space 10 to the power of negative 2 end exponent comma what is the concentration of O3?v 

Solution

The given reversible reaction is
                    3 straight O subscript 2 left parenthesis straight g right parenthesis space rightwards harpoon over leftwards harpoon space space space 2 straight O subscript 3 left parenthesis straight g right parenthesis
Applying the law of chemical equilibrium
                     straight K subscript straight c space equals space open square brackets straight O subscript 3 left parenthesis straight g right parenthesis close square brackets squared over open square brackets straight O subscript 2 left parenthesis straight g right parenthesis close square brackets cubed                      ...(1)
Putting this value in expression (1), we have
     
2.0 space cross times space 10 to the power of negative 50 end exponent space equals space fraction numerator open square brackets straight O subscript 3 left parenthesis straight g right parenthesis close square brackets squared over denominator left parenthesis 1.6 space cross times space 10 to the power of negative 2 end exponent right parenthesis cubed end fraction
or space space space space open square brackets straight O subscript 3 left parenthesis straight g right parenthesis close square brackets squared space equals space left parenthesis 2.0 space cross times space 10 to the power of negative 50 end exponent right parenthesis space left parenthesis 1.6 space cross times space 10 to the power of negative 2 end exponent right parenthesis cubed
space space space space space space space space space space space space space space space space space space space equals space 8.192 space cross times space 10 to the power of negative 56 end exponent
or space space space open square brackets straight O subscript 3 left parenthesis straight g right parenthesis close square brackets space equals space 2.86 space cross times space 10 to the power of negative 28 end exponent straight M