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Equilibrium

Question
CBSEENCH11006364

How is equilibrium constant expressed when the reaction is carried in the gaseous phase ?

Solution
When the reaction is carried in the gaseous phase, the equilibrium constant is expressed as To illustrate this, let us consider a purely gaseous reaction
mA left parenthesis straight g right parenthesis space plus space nB left parenthesis straight g right parenthesis space space rightwards harpoon over leftwards harpoon space xC left parenthesis straight g right parenthesis space plus space yD left parenthesis straight g right parenthesis
In this case, we shall consider the partial pressure of the gases to indicate their concentrations. The equilibrium constant (Kp) is expressed as
straight K subscript straight p space equals space fraction numerator left parenthesis straight p subscript straight C right parenthesis to the power of straight X space cross times space left parenthesis straight p subscript straight D right parenthesis to the power of straight y over denominator left parenthesis straight p subscript straight A right parenthesis to the power of straight m space cross times space left parenthesis straight p subscript straight B right parenthesis to the power of straight n end fraction
where PA, PB, PC and PD denote partial pressures of the respective gases.