-->

Thermodynamics

Question
CBSEENCH11006236

The tendency of a system to acquire a state of maximum randomness is the sole criterion for the spontaneity of a process. Comment.

 

Solution

No, there is a natural tendency of a system to attain a state of the greater randomness i.e. more disordered state. For example,
(i) There is more randomness on mixing of two gases (which do not react chemically).
(ii) Evaporation of water. The evaporation of water results in increase of randomness because the molecules in the vapour state have more randomness than in the liquid state
   straight H subscript 2 straight O left parenthesis straight l right parenthesis space space space rightwards arrow space space straight H subscript 2 straight O left parenthesis straight g right parenthesis
(iii) Dissolution of ammonium chloride in water. Solid ammonium chloride has less randomness while in solution ammonium chloride particles move freely as space NH subscript 4 superscript plus space and space Cl to the power of minus space ions and hence randomness increases. 
  NH subscript 4 Cl left parenthesis straight s right parenthesis space plus space water space space space rightwards arrow space space space space NH subscript 4 superscript plus left parenthesis aq right parenthesis space plus space Cl to the power of minus left parenthesis aq right parenthesis
If the randomness factor were the only criterion, then the process like liquefaction of gas or solidification of a liquid would not have been feasible since these were accompanied by a decrease in randomness. Hence the tendency of a system to acquire a state of maximum randomness is not the sole criterion for determining the spontaneity of the process.