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Thermodynamics

Question
CBSEENCH11006234

What do you understand by spontaneous and non-spontaneous processes? 

Solution

Spontaneous process. A process which has a natural tendency to take place either by itself or after initiation under a given set of conditions is known as a spontaneous process. For example,
(i) Sugar dissolve in water and forms a solution.
Sugar + water  rightwards arrow Solution of sugar in water
(ii) In the domestic oven, coal keeps on burning once ignited.
straight C left parenthesis straight s right parenthesis space plus space straight O subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow for ignition of space CO subscript 2 left parenthesis straight g right parenthesis
Non-spontaneous process: A process that has no natural tendency or urge to take place is called non-spontaneous process. However, many non-spontaneous processes can also be made to take place by supplying energy continuously from some external sources. For example:

(i) Water can be made to flow uphill by the use of an electric motor pump.
(ii) Electrolysis of water to separate it into pure hydrogen and pure oxygen.