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Thermodynamics

Question
CBSEENCH11006181

What do you mean by enthalpy (heat) of combustion? Give three examples.

Solution
It is the enthalpy change accompanying the complete combustion of one mole of a substance in excess of oxygen or air e.g.
(i) Combustion of carbon:
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(ii) Combustion of methane:
   CH subscript 4 left parenthesis straight g right parenthesis space plus space 2 straight O subscript 2 left parenthesis straight g right parenthesis space space space rightwards arrow space CO subscript 2 left parenthesis straight g right parenthesis space plus space 2 straight H subscript 2 straight O left parenthesis l right parenthesis semicolon
space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space increment straight H space equals space minus 890.3 space kJ
(iii) Combustion of ethyl alcohol:
        straight C subscript 2 straight H subscript 5 OH left parenthesis straight l right parenthesis space plus space 3 straight O subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space space 2 CO subscript 2 left parenthesis straight g right parenthesis space plus space 3 straight H subscript 2 straight O left parenthesis straight l right parenthesis semicolon
space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space increment straight H space equals negative 1367.4 space kJ