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Thermodynamics

Question
CBSEENCH11006178

Explain the origin of enthalpy change in a direction. interest

Solution

During the reformation of chemical bonds, when the energy required to break bonds is less than the energy released in the formation of new bonds, the chemical reaction would be exothermic i.e. heat would be evolved. e.g.
          CH subscript 4 left parenthesis straight g right parenthesis space plus space 2 straight O subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space CO subscript 2 left parenthesis straight g right parenthesis space plus space 2 straight H subscript 2 straight O space left parenthesis straight l right parenthesis semicolon
space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space increment straight H space equals space minus 890.3 space kJ space space space space space space space space space space space space space space space space space space space space
Similarly, when the energy required to break bonds is more than the energy released in the formation of new bonds for products, a chemical reaction would be endothermic and ∆H would be positive. For example,
 straight N subscript 2 left parenthesis straight g right parenthesis space plus space straight O subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space 2 NO left parenthesis straight g right parenthesis semicolon space space increment straight H space equals space plus 180.5 space kJ
In gaseous phase, the enthalpy change (∆H) of a chemical reaction can be written as
bold increment bold H bold space bold equals bold space bold Energy bold space bold reqd bold. bold space bold to bold space bold break bold space bold bonds bold space bold of bold space bold reactants
bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold minus bold left square bracket bold Energy bold space bold released bold space bold to bold space bold form bold space bold new bold space bold bonds bold space bold of bold space bold products bold right square bracket
bold space bold space bold H subscript bold 2 bold left parenthesis bold g bold right parenthesis bold plus bold Cl subscript bold 2 bold left parenthesis bold g bold right parenthesis bold space bold rightwards arrow bold space bold 2 bold HCl bold space bold left parenthesis bold g bold right parenthesis bold semicolon bold space bold increment bold H bold space bold equals bold space bold minus bold 185 bold space bold kJ
bold or bold space bold space bold space bold space bold space bold H bold space bold minus bold space bold H bold left parenthesis bold g bold right parenthesis bold space bold space bold plus bold space bold Cl bold space bold minus bold Cl bold left parenthesis bold g bold right parenthesis bold space bold rightwards arrow bold space bold space bold 2 bold HCl bold space bold left parenthesis bold g bold right parenthesis bold semicolon bold space
bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold increment bold H bold equals bold minus bold 185 bold space bold kJ
therefore space
space minus 185 space kJ space equals space left square bracket Energy space required space to space break space left parenthesis straight H space minus space straight H right parenthesis
space and space Cl space minus space Cl space bonds right square bracket space minus open square brackets 2 space cross times space Energy space released space to space form space straight H minus Cl space bond close square brackets