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Thermodynamics

Question
CBSEENCH11006172

Define the terms:
(i) Chemical energetics
(ii) Thermochemistry.

Solution
(i) Chemical energetics: It is the branch of chemistry that deals with energy changes during various physical processes and chemical reactions. These energy changes may be in the form of heat, light, electricity or mechanical work.
For example:
(a) Heat energy is liberated when carbon burns in air together with a glow of light.
straight C left parenthesis straight s right parenthesis space plus space straight O subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space space CO subscript 2 left parenthesis straight g right parenthesis space plus space Heat
(b) Magnesium ribbon when burnt in air produce mainly light energy.
2 Mg left parenthesis straight g right parenthesis space plus space straight O subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space 2 MgO left parenthesis straight s right parenthesis space plus space Ligh space energy
(c) The redox reaction between Zn and CuSOcarried out indirectly in Daniel cell produces electrical energy.
Zn left parenthesis straight s right parenthesis space plus space CuSO subscript 4 left parenthesis aq right parenthesis space space rightwards arrow space space ZnSO subscript 4 left parenthesis aq right parenthesis space plus space Cu left parenthesis straight s right parenthesis space plus space Electrical space energy.
(ii) Thermochemistry: It is the branch of chemistry that deals with the heat changes accompanying chemical reactions.