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Thermodynamics

Question
CBSEENCH11006054

State with reason whether the work is done by the system on the surroundings or on the system by the surroundings if the following change occurs at constant pressure:
Sn left parenthesis straight s right parenthesis space plus space 2 Cl subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space SnCl subscript 4 left parenthesis straight s right parenthesis

Solution

Work is done on the system by surroundings since there is 2 mol of gaseous reactants while there is no gaseous product. The result is decreased in volume i.e. w is positive.