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States Of Matter

Question
CBSEENCH11005914

With the help of Boyle's and Charle's laws, derive an expression for the ideal gas equation.

Solution

Derivation of the ideal gas equation: Let the volume of a given mass of a gas change from V1 to V2 when the pressure is changed from Pi to P2 and temperature is changed from T1 to T2. Suppose this change from initial state (P1 V1T1) to final state (P2V2T2) occurs in two steps:
First step: Suppose the volume of the given mass of the gas changes from V1 to Vx when pressure is changed from P1 to P2, keeping temperature T1 constant.
therefore space space space space According space to space Boyle apostrophe straight s space law comma
straight P subscript 1 straight V subscript 1 space equals space straight P subscript 2 straight V subscript 2 space left parenthesis Temperature space and space mass space of space gas space constant right parenthesis
or space space space space straight V subscript 2 space equals space fraction numerator straight P subscript 1 straight V subscript 1 over denominator straight P subscript 2 end fraction space space space space space space space space space space... left parenthesis 1 right parenthesis
Second step: Now let the volume changed from Vx to V2 when the temperature is changed from T1 to T2, keeping pressure P2 constant.
therefore     According to Charle's law,
                      straight V subscript 1 over straight T subscript 1 space equals space straight V subscript 2 over straight T subscript 2
or space space space space space space space space straight V subscript 1 space space equals space fraction numerator straight V subscript 2 straight T subscript 1 over denominator straight T subscript 2 end fraction space space space space space space space space space space... left parenthesis 2 right parenthesis
From (1) and (2), we have
              fraction numerator straight P subscript 1 straight V subscript 1 over denominator straight P subscript 2 end fraction space equals space fraction numerator straight V subscript 2 straight T subscript 1 over denominator straight T subscript 2 end fraction
or space space space fraction numerator straight P subscript 1 straight V subscript 1 over denominator straight T subscript 1 end fraction space equals space fraction numerator straight P subscript 2 straight V subscript 2 over denominator straight T subscript 2 end fraction space space space space space space space space space space space space space space space space space space space... left parenthesis 3 right parenthesis
or space space space space space PV over straight T space equals space straight k space space space space where space straight K space is space constant space space... left parenthesis 4 right parenthesis
The numerical value of the constant K is independent of the nature of the gas but depends on upon the amount of the gas. But at constant temperature and pressure the volume of a gas is proportional to the number of moles (n), this means that K is directly proportional to the number of moles (n).
or space space space straight K space proportional to space space space straight n
straight i. straight e. space space space space straight K space equals space nR space space space space space space space space space space space space space space space space space space space space space space space space space... left parenthesis 5 right parenthesis
where R is a constant of proportionality which is independent of nature as well as the amount of the gas and is known as a universal gas constant. From (4) and (5)
  space space space space space space space PV over straight T space equals space nR
or space space space space space space space space space PV space equals space nRT space space space space space space space space space space... left parenthesis 6 right parenthesis
Equation (6) is known as an ideal gas equation. Alternative derivation of ideal gas equation
: According to Boyle’s law,
                space straight V proportional to space 1 over straight P space space space space space space space space space space space space space open square brackets at space constant space straight T space and space straight n close square brackets space space space space... left parenthesis 1 right parenthesis
According to Charle's law,
 
 straight V proportional to space space straight T space space space space space left square bracket at space constant space straight P space and space straight n right square bracket space space space space... left parenthesis 2 right parenthesis
According to Avogadro's law,
 
 straight V space proportional to space space straight n space space space space space space open square brackets at space constant space straight P space and space straight T close square brackets space space space... left parenthesis 3 right parenthesis
Combining (1), (2) and (3), we have,
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or space space space space straight V space equals space straight R nT over straight P
or space space space space space PV space equals space nRT