With the help of Boyle's and Charle's laws, derive an expression for the ideal gas equation.
Derivation of the ideal gas equation: Let the volume of a given mass of a gas change from V1 to V2 when the pressure is changed from Pi to P2 and temperature is changed from T1 to T2. Suppose this change from initial state (P1 V1T1) to final state (P2V2T2) occurs in two steps:
First step: Suppose the volume of the given mass of the gas changes from V1 to Vx when pressure is changed from P1 to P2, keeping temperature T1 constant.
Second step: Now let the volume changed from Vx to V2 when the temperature is changed from T1 to T2, keeping pressure P2 constant. According to Charle's law,
From (1) and (2), we have
The numerical value of the constant K is independent of the nature of the gas but depends on upon the amount of the gas. But at constant temperature and pressure the volume of a gas is proportional to the number of moles (n), this means that K is directly proportional to the number of moles (n).
where R is a constant of proportionality which is independent of nature as well as the amount of the gas and is known as a universal gas constant. From (4) and (5)
Equation (6) is known as an ideal gas equation. Alternative derivation of ideal gas equation
: According to Boyle’s law,
According to Charle's law,
According to Avogadro's law,
Combining (1), (2) and (3), we have,
.