Using a molecular orbital diagram, predict the bond order, stability and magnetic character of O2–,O2+, and . Also, write their electronic configurations.
O2–(Superoxide ion): This ion is formed by the addition of one electron.
O2 + e- → O2
This additional electron will be added up in the molecular orbital.
Electronic configuration:
Bond order:
Here Nb = 8; Na = 5
Stability : As the bond order is positive, it is quite stable.
Magnetic character: It has one unpaired electron in the molecular orbital.
therefore, it is paramagnetic.
O+2 ion This ion is formed by the loss of one electron from O2 molecule.
O2 →O2+ e–
This electron will be lost from *2px or
*2py molecular orbital.
Electronic configuration:
Bond order: Here Nb = 8; Na = 3
Stability: As the bond order is positive, it is quite stable.
Magnetic character: Since ion has one unpaired electron in the
orbital, therefore, it is paramagnetic.
: The ion is formed when O2 molecule gains two electrons
These two electrons will be added to the *2px and
*2py molecular orbitals, one in each.
Electronic configuration:
Bond order: Here Nb = 8; Na = 6
Stability: As the bond order is positive, it is quite stable.
Magnetic character: As one of the molecular orbital has a unpaired electron, it is diamagnetic.