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Chemical Bonding And Molecular Structure

Question
CBSEENCH11005703

Discuss the orbital shapes of the following covalent molecules:
(i) H2 (ii) F2 (iii) O2 (iv) N2.

Solution
(i) H2 molecule: The electronic configuration of hydrogen is 1s1. Half filled orbital of one hydrogen atom overlaps with that of the other hydrogen having an electron in opposite spin to from H2 molecule.

(ii) F2 molecule: The F2 molecule is formed by the overlapping of two half filled p-orbitals of two fluorine atoms. The electronic configuration of Fluorine is 1s2 2s2 2p5. Thus Overlapping of the orbital forms F2 molecule.

(iii) O2 molecule: The electronic configuration of oxygen (Z = 8) is 1 straight s squared space 2 straight s squared space 2 straight p subscript straight x superscript 2 space 2 straight p subscript straight y superscript 1 space 2 straight p subscript straight z superscript 1.
Thus oxygen atom has two half filled atomic orbitals. The oxygen molecule is formed when two half filled p-orbitals of each oxygen atom overlap with the two half filled p-orbitals of the other oxygen atom. This results in the formation of a double bond between two oxygen atoms (O = O).

(iv) N2 molecule: The electronic configuration of nitrogen atom (Z = 7) is 1 straight s squared space 2 straight s squared space 2 straight p subscript straight x superscript 1 space space 2 straight p subscript straight y superscript 1 space 2 straight p subscript straight z superscript 1. 

The nitrogen atom has three half filled atomic orbitals. In the formation of N2 molecule, each of the three half, filled orbitals of one nitrogen atom overlaps with the three half filled orbitals of the other nitrogen atom.
This leads to the formation of a triple bond between two nitrogen atoms (N ≡ N).