-->

Classification Of Elements And Periodicity In Properties

Question
CBSEENCH11005553

The first left parenthesis increment subscript straight i straight H subscript 1 right parenthesis and the second left parenthesis increment subscript straight i straight H subscript 2 right parenthesis ionization enthalpies (in  kJ mol-1) and the left parenthesis increment subscript eg straight H right parenthesis electron gain enthalpy (in kJ mol-1) of a few elements are given below:
Elements            increment straight H subscript 1               increment straight H subscript 2                 increment subscript eg straight H
I                        520                    7300                    -60
II                       419                     3051                   -48
III                      1681                    3374                  -328
IV                       1008                    1846                 -295
V                         2372                    5251                 +48
VI                        738                      1451                -40  
Which of the above elements is likely to be:
(a) the least reactive element.
(b) the most reactive metal.
(c) the most reactive non-metal.
(d) the least reactive non-metal.
(e) the metal which can form a stable binary halide of the formula MX2(X =halogen).
(f) the metal which can form a predominantly stable covalent halide of the formula MX(X= halogen)?

Solution

Element V is likely to be the least reactive element. This is because it has the highest first ionisation enthalpy (ΔiH1) and a positive electron gain enthalpy (ΔegH).It is a noble gas

 (b) Element II is likely to be the most reactive metal as it has the lowest first ionisation enthalpy (ΔiH1) and a low negative electron gain enthalpy (ΔegH).The with lowest first ionisation enthalpy is likely to be a reactive metal

(c) Element III is likely to be the most reactive non–metal as it has a high first ionisation enthalpy (ΔiH1) but less than the noble gas elements and the highest negative electron gain enthalpy (ΔegH).

(d) Element V is likely to be the least reactive non–metal since it has a very high first ionisation enthalpy (ΔiH2) and a positive electron gain enthalpy (ΔegH).

 (e) Element VI has a low negative electron gain enthalpy (ΔegH). Thus, it is a metal. Further, it has the lowest second ionisation enthalpy (ΔiH2). Hence, it can form a stable binary halide of the formula MX2 (X=halogen).

 (f) The element I have low first ionisation energy and high second ionisation energy. Therefore, it can form a predominantly stable covalent halide of the formula MX (X=halogen).