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Classification Of Elements And Periodicity In Properties

Question
CBSEENCH11005431

Are the oxidation state and covalency of Al in open square brackets AlCl left parenthesis straight H subscript 2 straight O right parenthesis subscript 6 close square brackets to the power of 2 plus end exponent same?

Solution

Valency of chlorine = (-1)
Valency of water = 0
Let the oxidation state of Al be x.
           x -1         0
       [Al Cl   (H2O)6]2+
therefore        x - 1 + 6(0) = +2
or                         x = +3
Thus the oxidation state of Al is +3. Since six legends (which can denote a pair of electrons) i.e. H2O molecules are attached to the alumninum atom, thereofre, its covalency is 6.