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Classification Of Elements And Periodicity In Properties

Question
CBSEENCH11005498

Why is ionisation enthalpy of Be more than that of B?

Solution

The electronic configuration of Be (Z = 4) and B(Z = 5) are,

(i) The electronic configuration of Be in which all the occupied orbitals are fully filled is more stable than boron.
(ii) It is relatively easier to remove electron from 2p subshell in boron than removal of electrons from 2s subshell in Be as 2p orbital is less penetrating than 2s orbital. Therefore, 2p electron of B is less firmly held by the nucleus and so, it is relatively easily removed.