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Classification Of Elements And Periodicity In Properties

Question
CBSEENCH11005485

What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F-  (ii) Ar    (iii) Mg2+   (iv) Rb+ 

Solution

Ions of different elements which have the same number of electrons but different magnitude of the nuclear charge are called isoelectronic ions.


(i) Since F- has 10 electrons, therefore N3- (7 + 3), O2- (8 + 2), Ne (10 + 0),  Na+ (11 - 1), Mg2+ (12 - 2): Al3+ (13 - 3) are isoelectronic, as each one of these contains 10 electrons.


(ii) As Ar has 18 electrons, therefore P3- (15 + 3), S2- (16 + 2), Cl- (17 + 1), K+ (19 - 1), Ca2+ (20 - 2) are isoelectronic with it as cach one of each contains 18 electrons.


(iii) As Mg2+ has 10 electrons, therefore N3+ F , Ne, Na+, Al3+ are isoelectric with it as each one of these contains 10 electrons.


(iv) As Rb+ has 36 electron, therefore Br- (35 + 1), Kr (36 + 0) and Sr2+ (38 -2) are isoelectronic with it as each one of these contains 36 electrons.