What do you understand by iso-electronic ions? In iso-electronic ions, the value of ionic radius decreases with the increase in atomic number. Explain.
Isoelectronic ions are those which have a same number of electrons and hence same electronic configuration but the different magnitude of nuclear charge. A set of species (cations or anions) having the same number of electrons is known as iso-electronic series, e.g. N3-, O2-, F-, Na+, Mg+, Al3+ are isoelectronic species.
Within the series of isoelectronic ions, as the atomic number or nuclear charge increases, the attractive force between the nucleus and a same number of electrons also increases. This results in the decrease of ionic radius.
For example,
Ion =N3- O2- F- Na+ Mg+ Al3+
No. of electrons = 10 10 10 10 10 10
At. No = 7 8 9 11 12 13
Since, the size of the iso-electronic ion decreases with the increase in atomic number, the order of decreasing size is
N3- > O2- > F- > Na+ > Mg2+ > Al3+