Sponsor Area

Structure Of Atom

Question
CBSEENCH11005293

Emission transitions in the Paschen series end at orbit n = 3 and start from orbit n and can be represented as
v = 3.29 x 1015 (Hz) [1/32- l/n2.]

Calculate the value of n if the transition is observed at 1285 nm. Find the region of the spectrum.

Solution
space space space Here comma space space straight v space equals space 3.29 space cross times space 10 to the power of 15 left parenthesis Hz right parenthesis space open square brackets 1 over 3 squared minus 1 over straight n squared close square brackets space... left parenthesis 1 right parenthesis
space Also comma space straight v equals space straight c over straight lambda space equals space fraction numerator 3.0 space cross times space 10 to the power of 8 space ms to the power of negative 1 end exponent over denominator 1285 space cross times 10 to the power of negative 9 end exponent straight m end fraction space space space space... left parenthesis 2 right parenthesis
space From space equations space left parenthesis 1 right parenthesis space and space left parenthesis 2 right parenthesis comma space we space have
space space space space 3.29 space cross times space 10 to the power of 15 open square brackets 1 over 3 squared minus 1 over straight n squared close square brackets space equals space fraction numerator 3.0 space cross times space 10 to the power of 8 over denominator 1285 space cross times 10 to the power of negative 9 end exponent end fraction
space or space space space 1 over 9 minus 1 over straight n squared fraction numerator 3.0 space cross times space 10 to the power of 8 over denominator 1285 space cross times space 10 to the power of negative 9 end exponent space cross times space 3.29 space cross times space 10 to the power of 15 end fraction equals 0.071
space or space space 1 over straight n squared space equals space 1 over 9 minus 0.071 space equals space 0.111 minus 0.071
space space space space space space space space space space space equals space 0.04 space equals space 1 over 25
or space space space straight n squared space equals space 25 space space space or space space space straight n space equals space 5
The radiation corresponding to 1285 nm lies in the infra red region.