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Structure Of Atom

Question
CBSEENCH11005164

When white light that has passed through sodium vapours in viewed through a spectroscope, the observed spectrum has dark line at 5890Å. Explain this observation.

Solution
This indicates that the radiation corresponding to the wavelength 5890Å is absorbed from white light by sodium atoms for the excitation of electrons. The missing radiations appear as dark line in the emission spectra.