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Some Basic Concepts Of Chemistry

Question
CBSEENCH11005009

Carbon and oxygen are known to form two compounds. The carbon content in one of these is 42·9% while in the other it is 27·3%. Show that this data is in agreement with the law of multiple proportions. 

Solution
In first compound:
Weight percent of carbon = 42.9
Weight percent of oxygen = 100 - 42.9 = 57.1
In second compound:
Weight percent of carbon = 27.3
Weight percent of oxygen = 100 - 27.3 = 72.7
Now in first compound:
57.1 parts by weight of oxygen combine with 42.9 parts by weigh of carbon
therefore 1 part by weight of oxygen will combine withfraction numerator 42.9 over denominator 57.1 end fraction space equals space 0.751 space parts space of space carbon

Now in second compound:
72.7 parts by weight of oxygen combine with 27.3 parts by weight of carbon
 therefore 1 part by weight of oxygen will combine with fraction numerator 27.3 over denominator 72.7 end fraction space equals space 0.375 space parts of carbon.
The weights of carbon which combine with same weights of oxygen in two compounds bear a ratio 0·751 : 0·375 or 2 : 1. This is a simple ratio. Hence, the data illustrates the law of multiple proportion.