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Some Basic Concepts Of Chemistry

Question
CBSEENCH11005069

Balance the given skeleton equation by partial equation method:

NaOH space plus Cl subscript 2 space rightwards arrow space space NaCl plus NaClO subscript 3 plus straight H subscript 2 straight O

Solution

It involves the following steps:
(i) Chlorine reacts with water to form hydrochloric acid and hypochlorous acid.
     Cl subscript 2 plus straight H subscript 2 straight O space space space rightwards arrow space space space space space HCl space plus space HClO            ...(1)
(ii) Hydrochloric acid then reacts with sodium hydroxide to give sodium chloride and water.
HCl plus NaOH space rightwards arrow space space space NaCl space plus space straight H subscript 2 straight O                ...(2)
(iii) Hypochlorous acid reacts with sodium hydroxide to give sodium hypochlorite and water.
HClO plus NaOH space rightwards arrow space space space NaClO plus straight H subscript 2 straight O               ...(3)
(iv) Sodium hypochlorite decomposes to give sodium chlorate.
3 NaClO space rightwards arrow space space space NaClO subscript 3 plus 2 NaCl space space space space space space space space... left parenthesis 4 right parenthesis
Multiply the partial equations (1), (2) and (3) by 3 and add all the four equations.
space space open square brackets Cl subscript 2 plus straight H subscript 2 straight O space space space space rightwards arrow space space space space HCl space plus space HClO close square brackets space cross times space 3
open square brackets HCl plus NaOH space space rightwards arrow space space space space NaCl space plus straight H subscript 2 straight O close square brackets cross times 3
open square brackets HClO plus NaOH space rightwards arrow space space NaClO space plus straight H subscript 2 straight O close square brackets cross times 3
space space space space space space space space space space space space 3 NaClO space space rightwards arrow space space NaClO subscript 3 plus 2 NaCl
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3 Cl subscript 2 plus 6 NaOH space space space rightwards arrow space 5 NaCl plus NaClO subscript 3 plus 3 straight H subscript 2 straight O