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Some Basic Concepts Of Chemistry

Question
CBSEENCH11005043

A chemical compound is found to have the following composition: C = 19·5%, Fe = 15·2%, N = 22·8%, K = 41·5%. Calculate the empirical formula of the compound. What will be the molecular formula if the molecular mass of the compound is 368? Name the compound also. 

Solution
 (i) To calculate the empirical formula of the compound.

 
Empirical formula of the compound equals straight C subscript 6 FeN subscript 6 straight K subscript 4
(ii) To calculate the molecular formula of the compound:
Empirical formual mass = 6 x 12 + 56 +6 x 14 + 4 x 39
                                   = 72+56+84+156
                                    =368 (given)
Molecular mass = 368
         straight n space equals space fraction numerator Molecular space mass over denominator Empirical space formula space mass end fraction space equals space 368 over 368 space equals 1
Hence molecular formula is 
straight C subscript 6 FeN subscript 6 straight K subscript 4 space straight i. straight e. space straight K subscript 4 left square bracket Fe left parenthesis CN right parenthesis subscript 6 right square bracket
Name of compound is Potassium ferrocyanide.