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Hydrocarbons

Question
CBSEENCH11007861

Explain isomerism in arenes.

Solution

Arenes show position isomerism in their molecules. The isomers differ with respect to the relative positions of the alkyl substituents. In disubstituted derivates (-CH3 group on the substituent), three isomers are possible.

Similarly, three position isomers of trimethyl benzene are:

In the case of bicyclic arenes such as naphthalene, even monosubstituted compounds show position isomerism. For example.