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Hydrocarbons

Question
CBSEENCH11007842

How does acetylene react with:
(i) Gaseous chlorine
(ii) Liquid bromine?

Solution
 (i) With gaseous chlorine: Acetylene reacts with gaseous chlorine to form di or tetrachloride.

(ii) With liquid bromine: Acetylene reacts with liquid bromine to form tetrabromo derivative.

The red colour of bromine is discharged indicating the presence of unsaturation in the molecule.