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Hydrocarbons

Question
CBSEENCH11007839

Give two reactions of electrophilic addition on acetylene along with their mechanism.

Solution
(i) The addition of halogen: Chlorine and bromine add on to acetylene to form addition product.

Mechanism.  It involves electrophilic addition and consists of the following steps:

Step II. The electrophilic addition is repeated again when the final compound gets formed.

(ii) The addition of hydrogen halides. The hydrogen halides (HCl, HBr or HI) add-on triple bond to give rise to haloalkene or haloalkane.

Mechanism. It involves electrophilic addition and consists of the following steps: