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Hydrocarbons

Question
CBSEENCH11007801

How are alkenes prepared from Alkynes ?

Solution

Alkenes are prepared by the partial reduction of alkynes.
(a) Using Lindlar’s catalyst. Catalytic reduction of alkynes in the presence of palladium catalyst deposited over BaSO4 or CaSO4 and partially poisoned by S or quinoline (Lindlar’s catalyst) predominantly gives us alkenes.
stack CH subscript 3 minus straight C with But minus 2 minus yne below space identical to space straight C space minus space CH subscript 3 space plus space stack straight H subscript 2 space space rightwards arrow from straight S to Pd divided by CaCO subscript 3 of with left parenthesis Lindlar apostrophe straight s space catalyst right parenthesis below

(b) Using Birch reduction. If alkynes are reduced by sodium and liquid ammonia (Birch reduction), trans-alkenes are major products. 
stack CH subscript 3 minus straight C with But minus 2 minus yne below space identical to space straight C space minus CH subscript 3 space rightwards arrow with Na vertical line Liquid space NH subscript 3 on top