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Hydrocarbons

Question
CBSEENCH11007766

Why does the iodination of methane require an oxidising agent while so much reagent is needed in the chlorination and bromination of methane?

Solution

Iodine reacts with methane molecules reversibly. In fact, hydrogen iodide formed is a very strong reducing agent and it can convert iodomethane back to methane.
CH subscript 4 space plus space straight I subscript 2 space rightwards harpoon over leftwards harpoon space space stack CH subscript 3 straight I space plus space HI with Iodomethane below
To overcome this difficulty, iodination is generally carried out in the presence of strong oxidising agents like iodic acid (HIO3) which oxides HI formed during the reaction to iodine. 
HIO subscript 3 space plus space 5 HI space rightwards arrow space space 3 straight H subscript 2 straight O space plus space straight I subscript 2
On the other hand, during the chlorination or bromination of methane, no such reducing agent is produced.