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Organic Chemistry – Some Basic Principles And Techniques

Question
CBSEENCH11007630

How will you detect the presence of phosphorus in an organic compound?

Solution

Ammonium molybdate test: The organic compound is fused with a mixture of sodium carbonate and potassium nitrate. Phosphorus present is oxidised to sodium phosphate.
                   KNO subscript 3 space space rightwards arrow space space space KNO subscript 2 space plus space open square brackets straight O close square brackets space cross times space 5
3 Na subscript 2 CO subscript 3 space plus space 2 straight P space plus space 5 open square brackets straight O close square brackets space rightwards arrow space space 2 Na subscript 3 PO subscript 4 space plus space 3 CO subscript 2
The residue is extracted with water, boiled with some concentrated nitric acid, and then a hot solution of freshly prepared ammonium molybdate is added to it in excess. Formation of yellow precipitate or colouration indicates the presence of phosphorus in the given organic compound.
Na subscript 3 PO subscript 4 space plus space 3 HNO subscript 3 space space rightwards arrow space space stack straight H subscript 3 PO subscript 4 with Phosphoric space acid below space plus space 3 NaNO subscript 3

straight H subscript 3 PO subscript 4 space plus stack 12 left parenthesis NH subscript 4 right parenthesis subscript 2 MoO subscript 4 with Amm space molybodate below space plus space 21 HNO subscript 3 space rightwards arrow
space space space space space space space space space space space space stack left parenthesis NH subscript 4 right parenthesis subscript 3 PO subscript 4 12 MoO subscript 3 with Amm space phosphomolybdate below space plus 21 NH subscript 4 NO subscript 3 space plus 12 straight H subscript 2 straight O