-->

Organic Chemistry – Some Basic Principles And Techniques

Question
CBSEENCH11007618

How will you detect the presence of carbon and hydrogen in an organic compound ?

Solution

The detection of carbon and hydrogen in an organic compound is done by a single experiment. A small quantity of dry and powdered organic compound is mixed with 4-5 times its weight of dry cupric oxide. The mixture is taken in a hard glass test tube fitted with a delivery tube having a small bulb in it. The other end of the delivery tube is immersed in freshly prepared lime water taken in another test tube. In the bulb of the delivery tube, a small amount of anhydrous copper sulphate (white) is placed. The mixture is heated strongly when carbon and hydrogen present are oxidised to carbon dioxide and water respectively.

Carbon dioxide turns lime water milky whereas water vapours turn colourless copper sulphate blue. 

stack Ca left parenthesis OH right parenthesis subscript 2 space with Lime space water below plus space CO subscript 2 space space rightwards arrow space space stack CaCO subscript 3 with left parenthesis milkness right parenthesis below downwards arrow space plus space straight H subscript 2 straight O
stack CuSO subscript 4 with Anhydrous with copper space sulphate space left parenthesis white right parenthesis below below space plus space 5 straight H subscript 2 straight O space space rightwards arrow space space space space stack CuSO subscript 4. with Hydrated with copper space sulphate space left parenthesis Blue right parenthesis below below space 5 straight H subscript 2 straight O

Turning of lime water milky and of colourless copper sulphate blue shows the presence of carbon and hydrogen respectively.