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Organic Chemistry – Some Basic Principles And Techniques

Question
CBSEENCH11007575

Write resonance structures of CH= CH–CHO, indicate relative stability of the contributing structures.

Solution
The resonance structures of CH2 = CH – CHO can be written as:

Structure 1 is the most stable because each carbon and oxygen atom has an octet and no carbon or oxygen atom has a charge.
In structure II, the negative charge on the more electronegative atom and a positive charge on the more electropositive atom.
Structure III is least stable because more electronegative oxygen has a positive charge and electropositive carbon has a negative charge.