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Organic Chemistry – Some Basic Principles And Techniques

Question
CBSEENCH11007406

Which of the following carbocation is most stable?

  • left parenthesis CH subscript 3 right parenthesis subscript 3 straight C. straight C with plus on top straight H subscript 2
  • left parenthesis CH subscript 3 right parenthesis subscript 3 space straight C with plus on top
  • CH subscript 3 CH subscript 2 straight C with plus on top straight H subscript 2
  • CH subscript 3 straight C with plus on top HCH subscript 2 CH subscript 3

Solution

B.

left parenthesis CH subscript 3 right parenthesis subscript 3 space straight C with plus on top The order of stability of carbocation is 3° > 2° > 1°
left parenthesis straight a right parenthesis space stack open parentheses CH subscript 3 close parentheses subscript 3 straight C space minus space straight C with plus on top straight H subscript 2 with 1 degree space Carbocation below
left parenthesis straight b right parenthesis space stack left parenthesis CH subscript 3 right parenthesis subscript 3 straight C with plus on top with 3 degree space Carbocation below
left parenthesis straight c right parenthesis space space stack CH subscript 3 CH subscript 2 straight C with plus on top straight H subscript 2 with 1 degree space Carbocation below
left parenthesis straight d right parenthesis space space stack CH subscript 3 straight C with plus on top HCH subscript 2 CH subscript 3 with 2 degree space Carbocation below