-->

Organic Chemistry – Some Basic Principles And Techniques

Question
CBSEENCH11007457

What are hydrocarbons? Discuss their classification.

Solution

These are organic compounds which contain only two elements viz carbon and hydrogen.
Classification. These have been classified into two main classes:
(a) Open chain hydrocarbons or acyclic hydrocarbons
(b) Closed chain or cyclic hydrocarbons.
(a) Open chain hydrocarbons: These hydrocarbons contain an open chain of carbon atoms in their molecules which may be either straight chains or branched chains in nature.


These are also called aliphatic hydrocarbons and burn with a non-smoky flame. These have been further divided into two classes:
(a) Saturated hydrocarbons: These are open chain hydrocarbons which contain single covalent bonds between either carbon and carbon atoms (C – C) or carbon and hydrogen atoms (C – H). These are represented by the general formula CnH2n+2 where n is the number of carbon atoms. e.g.



(b) Unsaturated hydrocarbons: These are open chain hydrocarbons which contain carbon-carbon multiple bonds in their molecules. These are further classified as:
  (i) Alkenes:   These are unsaturated hydrocarbons which contain a double bond between two carbon atoms (>C= C<) in their molecules. These are represented by the general formula straight C subscript straight n straight H subscript 2 straight n end subscript where n is the number of carbon atoms. e.g.
  stack CH subscript 2 with Ethene below space equals space CH subscript 2 space space space space space space stack CH subscript 3 space minus space CH space equals space CH subscript 2 with Propene below space space space space space space stack CH subscript 3 space minus space CH space with But minus space 2 minus ene below equals space CH minus CH subscript 3
(ii) Alkynes: These are unsaturated hydrocarbons which contain a triple bond between two carbon atoms left parenthesis negative straight C space identical to space straight C minus right parenthesis
 in their molecules. 
 These are represented by the general formula straight C subscript straight n straight H subscript 2 straight n minus 2 end subscript where n is the number of carbon atoms. e.g. 
stack HC space identical to space CH with Ethyne below space space space stack CH subscript 3 space minus space straight C space identical to CH with Propyne below space space space space stack HC identical to straight C with But minus 1 minus yne below minus CH subscript 2 minus CH subscript 3

II. Closed chain or cyclic hydrocarbons. These hydrocarbons contain closed chains or ring of carbon atoms in their molecules. They are subdivided into two classes:
(i) Alicyclic hydrocarbons: These are hydrocarbons which contain rings of three or more carbon atoms in their molecules. They resemble aliphatic hydrocarbons in most of their characteristics. For example

(ii) Aromatic hydrocarbons. These have a cyclic system consisting of one or more hexagonal rings of carbon atoms with three double bonds in the alternate positions. The parent member of the family is benzene which is represented as:

All hydrocarbons containing a benzene type ring in their molecules are known as aromatic hydrocarbons or arenes.
Thus organic compounds containing one or more fused or isolated benzene rings and their functionalized derivatives are called aromatic compounds. For example,