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The P-Block Elements

Question
CBSEENCH11007355

What are silicates? Discuss briefly their structures.

Solution

Silicate is the general name given to a group of minerals which have silicon - oxygen bonds. Rocks, soils and clays consist of almost entirely silicate minerals such as quartz, mica, asbestos, feldspars and zeolites.
(i) Quartz is a crystalline form of silica (SiO2).
(ii) Mica is a potassium aluminium silicate KAl3Si3O10(OH)2.
(iii) Feldspar is a potassium silicate KAlSi3O8.
(iv) Asbestos is a calcium magnesium silicate CaMgSi2O6.
Structure: All silicates involve silicon-oxygen single bonds. These may either Si - O bonds or Si - O - bonds. The basic structural unit of all silicates is the SiO subscript 4 superscript 4 minus end superscript space ion. space In this ion, silicon is sp3 hybridised. Each sphybridised orbital of silicon combines with an orbital of the oxygen atom to form silicate ion which is tetrahedral in structure. 

Such tetrahedral units left parenthesis SiO subscript 4 superscript 4 minus end superscript right parenthesis are linked together in different ways to give chains, rings, sheets and three-dimensional networks.