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The P-Block Elements

Question
CBSEENCH11007281

What is the action of:
(a) H2O (b) LiH on B2H6?

Solution

(a) Action with water: Diborane is readily hydrolysed by water liberating H2 gas.
straight B subscript 2 straight H subscript 6 space plus space 6 straight H subscript 2 straight O space space rightwards arrow space space stack 2 straight H subscript 3 BO subscript 3 with Boric space acid below space plus space 6 straight H subscript 2
(b) Action with LiH: Diborane reacts with Lithium hydride in diethyl ether forming lithium borohydride.
  2 LiH space plus space straight B subscript 2 straight H subscript 6 space space rightwards arrow space space space stack 2 LiBH subscript 4 with Lithium space borohydride below