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The P-Block Elements

Question
CBSEENCH11007280

What are borones(boron hybrides)?

Solution

(i) Boron does not directly combine with hydrogen but a number of interesting hydrides are known. Boron hydrides such as B2H6 (diborane), B4H10 (tetraborane), B5H9 (pentaborane), B6H10 (hexaborane), B10H14 (decaborane) are collectively called boranes.
(ii) Preparation of diborane:
(a) By reducing boron trifluoride with lithium hybrid. 
8 BF subscript 3 space plus space 6 LiH space rightwards arrow with Heat on top space stack straight B subscript 2 straight H subscript 6 with Diborane below space plus space stack 6 LiBF subscript 4 with Lithium space boro space fluoride below
(b) By reducing boron trichloride with hydrogen or lithium aluminium hydride. 
          2 BCl subscript 3 space plus space 6 straight H subscript 2 space rightwards arrow with Heat on top space straight B subscript 2 straight H subscript 6 space plus space 6 HCl
4 BCl subscript 3 space plus space 3 LiAlH subscript 4 space rightwards arrow with Heat on top space 2 straight B subscript 2 straight H subscript 6 space plus space 3 AlCl subscript 3 space plus space 3 LiCl
Uses of diborane: It is used:
(i) as fuel for supersonic rockets.
(ii) as a reducing agent in organic reactions.
(iii) for preparing LiBH4, NaBH4 etc.