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The P-Block Elements

Question
CBSEENCH11007269

Give reasons:
Conc. HNOcan be transported in an aluminium container. 

Solution
When concentrated HNO3 is taken in an aluminium container, aluminium is oxidised to aluminium oxide (Al2O3). It forms a protective coating on the surface of the aluminium metal and checks further attack by the acid.
2 Al left parenthesis straight s right parenthesis space plus space 6 HNO subscript 3 left parenthesis conc. right parenthesis space rightwards arrow space space stack Al subscript 2 straight O subscript 3 left parenthesis straight s right parenthesis with Alumina below space plus space 6 NO subscript 2 left parenthesis straight g right parenthesis space plus space 3 straight H subscript 2 straight O left parenthesis straight l right parenthesis
Thus aluminium becomes positive and hence aluminium containers can be used to transport concentrated HNO3.