Sponsor Area

The S-Block Elements

Question
CBSEENCH11007174

Contrast the action of heat on the following and explain your answer:
(i) Na2CO3 and CaCO3
(ii) MgCl2.6H2O and CaCl2.6H2O
(iii) Ca(NO3)2 and NaNO3.

Solution

(i) Na2CO3 and CaCO2:
Na2CO3 does not decompose on heating while CaCO3 decomposes on heating to produce calcium oxide and carbon dioxide.
CaCO subscript 3 space rightwards arrow space space CaO space plus space CO subscript 2 
left parenthesis ii right parenthesis space MgCl subscript 2 6 straight H subscript 2 straight O space and space CaCl subscript 2 6 straight H subscript 2 straight O
left parenthesis straight a right parenthesis space MgCl subscript 2 6 straight H subscript 2 straight O space rightwards arrow with Heat on top space MgO space plus space 2 HCl space plus space 5 straight H subscript 2 straight O
left parenthesis straight b right parenthesis space CaCl subscript 2 6 straight H subscript 2 straight O space rightwards arrow with Heat on top space space CaCl subscript 2 space plus space 6 straight H subscript 2 straight O
left parenthesis iii right parenthesis space Ca left parenthesis NO subscript 3 right parenthesis subscript 2 space and space NaNO subscript 3 colon
left parenthesis straight a right parenthesis space 2 Ca left parenthesis NO subscript 3 right parenthesis subscript 2 space space rightwards arrow with Heat on top space 2 CaO space plus space 4 NO subscript 2 space plus space straight O subscript 2
left parenthesis straight b right parenthesis 2 NaNO subscript 3 space rightwards arrow with Heat on top space 2 NaNO subscript 2 space plus space straight O subscript 2